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Removing polybrominated diphenyl ethers in pure water using Fe/Pd bimetallic nanoparticles

Min ZHANG,Jian LU,Zhencheng XU,Yiliang HE,Bo ZHANG,Song JIN,Brian BOMAN

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 5,   Pages 832-839 doi: 10.1007/s11783-015-0778-x

Abstract: Polybrominated diphenyl ethers (PBDEs) have been widely used as fire-retardants.Palladium bimetallic nanoparticles (nZVI/Pd) were synthesized in this study to degrade decabromodiphenyl etherResults from this study suggest that nZVI/Pd may be an effective tool for treating polybrominated diphenyl

Keywords： degradation     bimetallic nanoparticles     nanoscale zero-valent iron     polybrominated diphenyl ethers    

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Photocatalytic degradation of polybrominated diphenyl ethers in pure water system

Min ZHANG,Jian LU,Yiliang HE,P Chris WILSON

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 2,   Pages 229-235 doi: 10.1007/s11783-014-0762-x

Abstract: Due to the low water solubility of polybrominated diphenyl ethers, organic solvent is usually added intoIn this study the photocatalytic degradation of decabromodiphenyl ether (BDE209), a type of polybrominateddiphenyl ether used throughout the world, in pure water without the addition of organic solvent was

Keywords： polybrominated diphenyl ethers     photocatalytic degradation     solvent    

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Legacies and health risks of heavy metals, polybrominated diphenyl ethers, and polychlorinated dibenzo-dioxins

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 7, doi: 10.1007/s11783-023-1679-z

Abstract:

● Heavy metals and organic toxins may persist in legacy sites for a long time.

Keywords： E-waste     Human health risk     Organ risk     Heavy metal toxicity     PBDE     PCDD/F    

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Joint effects of Penta-BDE and heavy metals on

Baohua TANG, Lingyan ZHU, Qixing ZHOU

Frontiers of Environmental Science & Engineering 2011, Volume 5, Issue 1,   Pages 99-110 doi: 10.1007/s11783-010-0260-8

Abstract: The joint toxicity of Penta-BDE (Pe-BDE) and heavy metals including cadmium and copper on ( ) was evaluated on the basis of determining the 48 h survival, antioxidative enzyme responses, and lipid peroxidation. The response was classified as additive, greater than additive, or less than additive by comparing the measured “toxic units, TU” with one. Based on the survival of , less-than-additive interactions were found in most of mixtures treatments. This may be attributed to the different toxicity mechanism between Pe-BDE and metals. Cu and Cd played a greater role in toxicity than what Pe-BDE did. As for the superoxide dismutase (SOD) and catalase (CAT) activity, most response was less than additive. For the glutathione -transferases (GST) activity, most of the greater-than-additive responses were found in the Cu plus Pe-BDE treatments, but the additive responses occurred in Cd plus Pe-BDE treatments and binary metal treatments. For lipid peroxide levels, which were measured as malondialdehyde (MDA) levels, less-than-additive response occurred in the 50% Cd plus 50% Cu and ternary mixture treatments. Results suggested that Pe-BDE, Cd, and Cu could induce different patterns of antioxidant enzyme responses, such as antioxidant/prooxidant responses, depending on their capability to produce reactive oxygen species and antioxidant enzymes to detoxify them.

Keywords： polybrominated diphenyl ethers (PBDEs)     heavy metal     mixture toxicity     toxic units (TUs)     antioxidant enzyme    

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Solvent-resistant porous membranes using poly(ether−ether ketone): preparation and application

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1536-1559 doi: 10.1007/s11705-022-2221-8

Abstract: Poly(ether−ether ketone) (PEEK) is a linear aromatic macromolecule, which can form semi-crystalline aggregative

Keywords： PEEK     phase inversion     solvent-resistant membrane     nanofiltration     membrane contactor    

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Sulfonated poly(ether ether ketone)/zirconium tricarboxybutylphosphonate composite proton-exchange membranes

GAO Qijun, HUANG Mianyan, WANG Yuxin, CAI Yuquan, XU Li

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 1,   Pages 95-101 doi: 10.1007/s11705-008-0012-5

Abstract: Sulfonated poly(ether ether ketone) (SPEEK) is a very promising alternative membrane material for direct

Keywords： homogeneous mixture     PBTC     zirconium tricarboxybutylphosphonate     Nafion115     DMFC    

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Synthesis and fluorescence behavior of 2,5-diphenyl-1,3,4-oxadiazole-containing bismaleimides and bissuccinimides

Xin ZHANG, Zichen LI

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 4,   Pages 381-387 doi: 10.1007/s11705-013-1359-9

Abstract: Bismaleimides bearing 2,5-diphenyl-1,3,4-oxadiazole chromophores at , , position and corresponding

Keywords： fluorescence     bismaleimide     oxadiazole     succinimide    

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Biomass to dimethyl ether by gasification/synthesis technology

Tiejun WANG, Yuping LI, Longlong MA, Chuangzhi WU

Frontiers in Energy 2011, Volume 5, Issue 3,   Pages 330-339 doi: 10.1007/s11708-010-0121-y

Abstract: Technical and economic analysis was done for the biomass to dimethyl ether (DME) technology to promote

Keywords： technical and economic analysis     biomass     dimethyl ether     gasification/synthesis    

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Direct synthesis of diphenyl carbonate over heterogeneous catalyst: effects of structure of substituted

WU Guangwen, JIN Fang, WU Yuxin, ZHANG Guangxu, LI Dinghuo, WANG Cunwen, MA Peisheng

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 1,   Pages 59-64 doi: 10.1007/s11705-007-0012-x

Abstract: Active component Pd was loaded on various perovskite supports for synthesis of diphenyl carbonate.

Keywords： photoelectron spectroscopy     diphenyl carbonate     proportion     diffraction     perovskite    

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Dimethyl ether as alternative fuel for CI engine and vehicle

Zhen HUANG , Xinqi QIAO , Wugao ZHANG , Junhua WU , Junjun ZHANG ,

Frontiers in Energy 2009, Volume 3, Issue 1,   Pages 99-108 doi: 10.1007/s11708-009-0013-1

Abstract: As a developing and the most populous country in the world, China faces major challenges in energy supply and environmental protection. It is of great importance to develop clean and alternative fuels for internal combustion engines. On the basis of researches on DME engine and vehicle at Shanghai Jiaotong University in the last twelve years, fuel injection, combustion, performance and exhaust emissions of DME engine and DME vehicle are introduced in this paper. The results indicate that DME engines can achieve high thermal efficiency and ultra low emissions, and will play a significant role in meeting the energy demand while minimizing environmental impact in China.

Keywords： dimethyl ether (DME)     fuel injection     combustion process     emission control     CI engine     vehicle    

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Study on direct alcohol/ether fuel synthesis process in bubble column slurry reactor

Zhen CHEN, Haitao ZHANG, Weiyong YING, Dingye FANG

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 4,   Pages 461-471 doi: 10.1007/s11705-010-0517-6

Abstract: The recent studies of direct alcohol/ether synthesis process in slurry reactors were reviewed, and theresearch work in our laboratory was carried out in this paper. a global kinetics model for direct dimethyl etherThe numerical simulations of reactor design of 100000 t/a dimethyl ether pilot plant indicate that higherpressure and lower temperature were favorable to the increase of CO conversion, selectivity of dimethyl ether

Keywords： syngas     alcohol/ether fuel     slurry catalyst     bubble column slurry reactor     global kinetics     mathematical model    

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A Kinetic Study on the Degradation of Diphenyl Ketone and Malachite Green in Water With 185 nmUV Irradiation

Wen Ruimei,Ge Weiwei

Strategic Study of CAE 2007, Volume 9, Issue 9,   Pages 40-46

Abstract:

In this paper,  the degradation kinetics of diphenyl ketone and A chemical kinetic equation is established and the kinetics rule for degradation of diphenyl ketone

Keywords： water     185 nmUV     diphenyl ketone     malachite green     kinetics    

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Enhanced debromination of 2,2′,4,4′-tetrabromodiphenyl ether (BDE-47) by zero-valent zinc with ascorbic

Chaojin Jiang, Xiaoqian Jiang, Lixun Zhang, Yuntao Guan

Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 3, doi: 10.1007/s11783-020-1224-2

Abstract: with ascorbic acid (ZVZ/AA) was developed and applied to debrominate the 2,2′,4,4′-Tetrabromodiphenyl ethermethanol/H2O (v:v= 4:6), which could convert approximately 94% of 5 mg/L BDE-47 into lower-brominated diphenyland gas chromatography mass spectrometry analyses revealed that bromine ion and lower-debromination diphenyldominant pathway for conversion of BDE-47 was sequential debromination and the final products were diphenyl

Keywords： 2     2′     4     4′-tetrabromodiphenyl ether (BDE-47)     Ascorbic acid     Reductive debromination     Zero-valent zinc    

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Exergy losses in premixed flames of dimethyl ether and hydrogen blends

Tongbin ZHAO, Jiabo ZHANG, Dehao JU, Zhen HUANG, Dong HAN

Frontiers in Energy 2019, Volume 13, Issue 4,   Pages 658-666 doi: 10.1007/s11708-019-0645-8

Abstract: A second-law thermodynamic analysis was conducted for stoichiometric premixed dimethyl ether (DME)/hydrogen

Keywords： second law analysis     flame     dimethyl ether (DME)     hydrogen     binary fuels    

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Removal of decabromodiphenyl ether (BDE-209) by sepiolite-supported nanoscale zerovalent iron

Rongbing FU,Na MU,Xiaopin GUO,Zhen XU,Dongsu BI

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 5,   Pages 867-878 doi: 10.1007/s11783-015-0800-3

Abstract: sepiolite as a supporter was used to investigate the removal kinetics and mechanisms of decabromodiphenyl ether

Keywords： sepiolite-supported nanoscale zerovalent iron     decabromodiphenyl ether     debromination     adsorption     mechanism    

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Title Author Date Type Operation

Removing polybrominated diphenyl ethers in pure water using Fe/Pd bimetallic nanoparticles

Min ZHANG,Jian LU,Zhencheng XU,Yiliang HE,Bo ZHANG,Song JIN,Brian BOMAN

Journal Article

Photocatalytic degradation of polybrominated diphenyl ethers in pure water system

Min ZHANG,Jian LU,Yiliang HE,P Chris WILSON

Journal Article

Legacies and health risks of heavy metals, polybrominated diphenyl ethers, and polychlorinated dibenzo-dioxins

Journal Article

Joint effects of Penta-BDE and heavy metals on

Baohua TANG, Lingyan ZHU, Qixing ZHOU

Journal Article

Solvent-resistant porous membranes using poly(ether−ether ketone): preparation and application

Journal Article

Sulfonated poly(ether ether ketone)/zirconium tricarboxybutylphosphonate composite proton-exchange membranes

GAO Qijun, HUANG Mianyan, WANG Yuxin, CAI Yuquan, XU Li

Journal Article

Synthesis and fluorescence behavior of 2,5-diphenyl-1,3,4-oxadiazole-containing bismaleimides and bissuccinimides

Xin ZHANG, Zichen LI

Journal Article

Biomass to dimethyl ether by gasification/synthesis technology

Tiejun WANG, Yuping LI, Longlong MA, Chuangzhi WU

Journal Article

Direct synthesis of diphenyl carbonate over heterogeneous catalyst: effects of structure of substituted

WU Guangwen, JIN Fang, WU Yuxin, ZHANG Guangxu, LI Dinghuo, WANG Cunwen, MA Peisheng

Journal Article

Dimethyl ether as alternative fuel for CI engine and vehicle

Zhen HUANG , Xinqi QIAO , Wugao ZHANG , Junhua WU , Junjun ZHANG ,

Journal Article

Study on direct alcohol/ether fuel synthesis process in bubble column slurry reactor

Zhen CHEN, Haitao ZHANG, Weiyong YING, Dingye FANG

Journal Article

A Kinetic Study on the Degradation of Diphenyl Ketone and Malachite Green in Water With 185 nmUV Irradiation

Wen Ruimei,Ge Weiwei

Journal Article

Enhanced debromination of 2,2′,4,4′-tetrabromodiphenyl ether (BDE-47) by zero-valent zinc with ascorbic

Chaojin Jiang, Xiaoqian Jiang, Lixun Zhang, Yuntao Guan

Journal Article

Exergy losses in premixed flames of dimethyl ether and hydrogen blends

Tongbin ZHAO, Jiabo ZHANG, Dehao JU, Zhen HUANG, Dong HAN

Journal Article

Removal of decabromodiphenyl ether (BDE-209) by sepiolite-supported nanoscale zerovalent iron

Rongbing FU,Na MU,Xiaopin GUO,Zhen XU,Dongsu BI

Journal Article